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Физика твердого тела, 2021, том 63, выпуск 7, страница 951 (Mi ftt10142)

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Synthesis and Luminescence of Ba$_2$ScCl$_7$

R. A. Bhoyara, A. C. Nayaka, S. P. Wankhedeb, P. D. Belsarec, S. V. Moharild

a RKDF University, Bhopal, India
b Department of Physics, K.D.K. College of Engineering, Nagpur, India
c Shri Ramdeobaba College of Engineering and Management, Nagpur, 440013, India
d Department of Physics, RTM Nagpur University, Nagpur, 440033, India

Аннотация: New results on luminescence in Ba$_2$ScCl$_7$ are reported. Lanthanides Eu$^{2+}$ and Ce$^{3+}$ were chosen as activators. The phosphors could be prepared by a simple wet chemical method. Reduction of europium to the divalent form could be achieved at 400$^\circ$C. Both activators exhibit strong photoluminescence (PL) originating in transitions from the lowest energy state of 4f$^{n-1}$15d$^1$ configuration to the ground state of 4f$^7$/4f$^1$ configuration. Simple preparation coupled with intense PL prompted us to suggest that these hitherto unexplored phosphors could be exploited for applications such as scintillator.

Ключевые слова: halide, photoluminescence, phosphor.

Поступила в редакцию: 24.02.2021
Исправленный вариант: 02.03.2021
Принята в печать: 03.03.2021

Язык публикации: английский


 Англоязычная версия: Physics of the Solid State, 2021, 63:6, 948–952


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