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ЖУРНАЛЫ // Физика твердого тела // Архив

Физика твердого тела, 2020, том 62, выпуск 1, страница 93 (Mi ftt8527)

Эта публикация цитируется в 5 статьях

Полупроводники

Sprayed NiO-doped $p$-type transparent ZnO thin films suitable for gas-sensing devices

Y. Aounab, R. Meneceura, S. Benramacheb, B. Maaouic

a Mechanical Department, Faculty of Technology, University of El-Oued, Algeria
b Laboratoire de Physique Photonique et Nanomatériaux Multifonctionnels, University of Biskra, Algeria
c VTRS Laboratory, Institute of Technology, University of El-Oued, Algeria

Аннотация: The spray pneumatic method has been successfully employed for the preparation of polycrystalline NiO-doped ZnO thin films. The effect of NiO content (0, 1, 2, 3, and 6 at.%) is studied on structural, optical, and electrical properties of NiO-doped ZnO thin films. The thin films were successfully deposited on a glass substrate at 450$^\circ$C using the organic solar heater. XRD patterns of NiO-doped ZnO thin films indicate that the obtained ZnO thin films are polycrystalline with (100), (002), and (101) highest peaks of ZnO phase. However, $\alpha$-Ni(OH)$_{2}$ and $\beta$-Ni(OH)$_{2}$ were observed at 6 and 3 at.% NiO, respectively. The crystal structure was improved for doped thin films, the crystallite size decreased by increasing the NiO content up to 6 at.% NiO. All thin films have a high optical transmission in the visible region of about 85%. The optical band gap energy decreased from 3.26 eV for 0% to 3.34 eV for 1 at.%, and further decreased to 3.27 eV for 6 at.% NiO. The thin film deposited with 3 at.% NiO has the lowest value of Urbach energy (0.091 eV). The electrical conductivity of the NiO-doped ZnO films increased greatly from 0.016 ($\Omega$ $\cdot$ cm)$^{-1}$ for 0% NiO to 0.042 ($\Omega$ $\cdot$ cm)$^{-1}$ for 3 at.% NiO. It can be noted that the deposited film after 3 at.% NiO is a $p$-type semiconductor.

Ключевые слова: ZnO, thin films, NiO-doping, transparent conductive oxides (TCO), spray pneumatic method.

Поступила в редакцию: 27.08.2019

Язык публикации: английский


 Англоязычная версия: Physics of the Solid State, 2020, 62:1, 131–136

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