H. Wang, N. Wu, J. Zheng, Ch. Zheng, D. Wang, “Synthesis and structures of two mononuclear iron(ii) complexes derived from polypyridine ligands”, Mendeleev Commun., 30:1 (2020), 100

Эта публикация цитируется в 3 статьях

Communications

Synthesis and structures of two mononuclear iron(ii) complexes derived from polypyridine ligands

H. Wang^ab, N. Wu^a, J. Zheng^a, Ch. Zheng^ab, D. Wang^a

^a Hubei Key Laboratory of Pollutant Analysis and Reuse Technology, Hubei Normal University, Huangshi, P.R. China
^b Department of Chemistry, The School of Art and Science of Hubei Normal University, Huangshi, P.R. China

Аннотация: Three polypyridine ligands such as tri(2-pyridyl)methane, (2,2’-bipyridin-6-yl)di(2-pyridyl)methane and 2,6-bis[di(2-pyridyl)methyl] pyridine as well as their new iron(II) mononuclear complexes have been obtained in a one-pot synthesis. Detailed structural analyses and magnetic susceptibility measurements confirm the expected six-coordinate octahedral geometry and the metric parameters are consistent with lowspin iron(II) in the complexes.

Ключевые слова: polypyridine, one-pot synthesis, metal complexes, low-spin.

Язык публикации: английский

DOI: 10.1016/j.mencom.2020.01.033

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