E. V. Nurieva, A. A. Alexeev, Yu. K. Grishin, V. A. Tafeenko, O. N. Zefirova, “New compounds with 4-azatricyclo[4.3.1.13,8]undecane framework”, Mendeleev Commun., 30:2 (2020), 145

Эта публикация цитируется в 3 статьях

Communications

New compounds with 4-azatricyclo[4.3.1.1^3,8]undecane framework

E. V. Nurieva^a, A. A. Alexeev^a, Yu. K. Grishin^a, V. A. Tafeenko^a, O. N. Zefirova^ab

^a Department of Chemistry, M.V. Lomonosov Moscow State University, Moscow, Russian Federation
^b Institute of Physiologically Active Compounds, Federal Research Center of Problems of Chemical Physics and Medicinal Chemistry, Russian Academy of Sciences, Chernogolovka, Moscow Region, Russian Federation

Аннотация: Reactions of 1-[(endo-bicyclo[3.3.1]non-6-en-3-yl)methyl]-3-tert-butylthiourea with I₂/Bu^tOOH and I₂/K₂CO₃ afforded 4-azatricyclo[4.3.1.1^3,8]undecane based products via intramolecular cyclization, as determined by X-ray analysis and NMR spectroscopy.

Ключевые слова: N-[(endo-bicyclo[3.3.1]non-6-en-3-yl)methyl]thiourea, intramolecular cyclization, bridged tricyclic compounds, ureas, thioureas, azahomoadamantanes, electrophilic addition.

Язык публикации: английский

DOI: 10.1016/j.mencom.2020.03.004

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