A. A. Musikhina, I. A. Utepova, O. N. Chupakhin, A. I. Suvorova, E. Yu. Zyryanova, “Regioselective synthesis of 1-azinyl-1′-isopropenylferrocenes”, Mendeleev Commun., 30:2 (2020), 209

Эта публикация цитируется в 3 статьях

Communications

Regioselective synthesis of 1-azinyl-1′-isopropenylferrocenes

A. A. Musikhina^ab, I. A. Utepova^ab, O. N. Chupakhin^ab, A. I. Suvorova^b, E. Yu. Zyryanova^b

^a I.Ya. Postovsky Institute of Organic Synthesis, Ural Branch of the Russian Academy of Sciences, Ekaterinburg, Russian Federation
^b Institute of Chemical Engineering, Ural Federal University, Ekaterinburg, Russian Federation

Аннотация: The Friedel–Crafts acetylation (Ac₂O/AlCl₃) reaction of azinylferrocenes occurs regioselectively at position 1′. Acetylated derivatives upon reaction with Ph₃P=CH₂ give the corresponding 1-azinyl-1′-isopropenylferrocenes.

Ключевые слова: ferrocenes, isopropenylferrocene, regioselective synthesis, Friedel–Crafts acylation, Wittig reaction, azines.

Язык публикации: английский

DOI: 10.1016/j.mencom.2020.03.026

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