N. M. Rubtsov, V. I. Chernysh, G. I. Tsvetkov, K. J. Troshin, I. O. Shamshin, A. P. Kalinin, “Ignition of hydrogen–oxygen and stoichiometric hydrogen–methane–oxygen mixtures on hot wires at low pressures”, Mendeleev Commun., 2020, том 30, выпуск 2,страницы 241

Эта публикация цитируется в 1 статье

Ignition of hydrogen–oxygen and stoichiometric hydrogen–methane–oxygen mixtures on hot wires at low pressures

N. M. Rubtsov^a, V. I. Chernysh^a, G. I. Tsvetkov^a, K. J. Troshin^b, I. O. Shamshin^b, A. P. Kalinin^c

^a A.G. Merzhanov Institute of Structural Macrokinetics and Materials Science, Russian Academy of Sciences, Chernogolovka, Moscow Region, Russian Federation
^b N.N. Semenov Federal Research Center for Chemical Physics, Russian Academy of Sciences, Moscow, Russian Federation
^c A.Yu. Ishlinsky Institute for Problems in Mechanics, Russian Academy of Sciences, Moscow, Russian Federation

Аннотация: It was found that the ignition temperatures of H2–O2 and H2–CH4–O2 mixtures at a low pressure on heated Pd, Pt, Nichrome and Kanthal wires at 40 Torr increase with a decrease in H2 concentration; only a heated Pd wire shows the pronounced catalytic action. Numerical calculations allowed us to reveal the role of an additional branching step, viz. H + HO2 - 2 OH.

Ключевые слова: ignition, temperature, hydrogen, methane, oxygen, heated wire, additional branching.

Язык публикации: английский

DOI: 10.1016/j.mencom.2020.03.038