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ЖУРНАЛЫ // Mendeleev Communications // Архив

Mendeleev Commun., 2020, том 30, выпуск 3, страницы 305–307 (Mi mendc1178)

Эта публикация цитируется в 6 статьях

Communications

Efficient one-pot synthesis of diphenyl(pyrazin-2-yl)phosphine and its AgI, AuI and PtII complexes

M. I. Rogovoya, M. P. Davydovaa, I. Yu. Bagryanskayab, A. V. Artem'eva

a A.V. Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, Novosibirsk, Russian Federation
b N.N. Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch of the Russian Academy of Sciences, Novosibirsk, Russian Federation


Аннотация: A convenient one-pot synthesis of diphenyl(pyrazin-2-yl)phosphine has been developed based on reaction of Ph3P with metallic lithium followed by treatment of the Ph2PLi formed with 2-chloropyrazine. The AgI, AuI and PtII chloride complexes derived from this phosphine have been synthesized and structurally characterized.

Ключевые слова: diphenyl(pyrazin-2-yl)phosphine, lithiation, pyrazine, triphenylphosphine, silver(I) complexes, gold(I) complexes, platinum(II) complexes.

Язык публикации: английский

DOI: 10.1016/j.mencom.2020.05.014



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