E. B. Rakhimova, V. Yu. Kirsanov, E. S. Meshcheryakova, A. G. Ibragimov, U. M. Dzhemilev, “Stereochemical outcome of perhydro hexaazadibenzotetracene formation from trans-1,2-diaminocyclohexane”, Mendeleev Commun., 30:3 (2020), 308

Эта публикация цитируется в 9 статьях

Communications

Stereochemical outcome of perhydro hexaazadibenzotetracene formation from trans-1,2-diaminocyclohexane

E. B. Rakhimova, V. Yu. Kirsanov, E. S. Meshcheryakova, A. G. Ibragimov, U. M. Dzhemilev

Institute of Petrochemistry and Catalysis, Ufa Federal Research Centre of the Russian Academy of Sciences, Ufa, Russian Federation

Аннотация: A one-pot reaction between (±)-trans-1,2-diaminocyclohexane and glyoxal affords intermediate perhydro-1,6,7,12-tetraazatetracene whose further treatment with formaldehyde and (het)arylamines in the presence of YbCl₃·6H₂O gives 2,9-di(het)aryl substituted (3bR*,7aR*,10bR*,14aR*)-perhydro-2,3a,7b,9,10a,14b-hexaazadibenzo[fg,op]tetracenes with cis-junction of the cycles along the C(14c)–C(14d) bond.

Ключевые слова: polyazapolycycles, catalysis, heterocyclization, trans-1,2-diaminocyclohexane, tetraazatetracenes, hexaazadibenzotetracenes.

Язык публикации: английский

DOI: 10.1016/j.mencom.2020.05.015

	*Дополнительные материалы:*
		Supplementary_data_1.pdf	2.5 Mb