I. S. Zhidkov, R. N. Maksimov, A. I. Kukharenko, L. D. Finkelstein, S. O. Cholakh, V. V. Osipov, E. Z. Kurmaev, “Effect of post-annealing in air on optical and XPS spectra of Y2O3 ceramics doped with CeO2”, Mendeleev Commun., 2019, том 29, выпуск 1,страницы 102

Эта публикация цитируется в 42 статьях

Effect of post-annealing in air on optical and XPS spectra of Y2O3 ceramics doped with CeO2

I. S. Zhidkov^a, R. N. Maksimov^bc, A. I. Kukharenko^a, L. D. Finkelstein^d, S. O. Cholakh^a, V. V. Osipov^b, E. Z. Kurmaev^ad

^a Institute of Physics and Technology, Ural Federal University, Ekaterinburg, Russian Federation
^b Institute of Electrophysics, Ural Branch of the Russian Academy of Sciences, Ekaterinburg, Russian Federstion
^c NANOTECH Centre, Ural Federal University, Ekaterinburg, Russian Federation
^d M.N. Mikheev Institute of Metal Physics, Ural Branch of the Russian Academy of Sciences, Ekaterinburg, Russian Federation

Аннотация: Yttrium oxide ceramics doped with CeO2 (5 mol%) were prepared from nanopowders produced by the laser ablation method. The optical measurements have demonstrated that the transparency of as-sintered ceramic was markedly increased after annealing (T = 1400 °C) under air. XPS data revealed the presence of mixed Ce3+ and Ce4+ states, while oxygen defect peak decreased after annealing owing to the defect elimination during oxygen diffusion into the highly defective ceramic.

Ключевые слова: Yttrium oxide, ceramic, electronic structure, XPS, transmission, annealing.

Язык публикации: английский

DOI: 10.1016/j.mencom.2019.01.035