V. A. Vil', E. S. Gorlov, O. V. Bityukov, I. B. Krylov, G. I. Nikishin, K. K. Pivnitsky, A. O. Terent'ev, “Oxidative C–O coupling as a new idea in the ‘click-like chemistry’: malonyl peroxides for the conjugation of two molecules”, Mendeleev Commun., 2019, том 29, выпуск 2,страницы 132

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Oxidative C–O coupling as a new idea in the ‘click-like chemistry’: malonyl peroxides for the conjugation of two molecules

V. A. Vil'^a, E. S. Gorlov^ab, O. V. Bityukov^a, I. B. Krylov^a, G. I. Nikishin^a, K. K. Pivnitsky^a, A. O. Terent'ev^a

^a N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation
^b D.Mendeleev University of Chemical Technology of Russia, Moscow, Russian Federation

Аннотация: Malonyl peroxides were used for the one-pot construction of hybrid structures by conjugation of heterocycle (3H-pyrazol-3-one, isoxazol-5(2H)-one, pyrazolidine-3,5-dione, or barbituric acid) and amine or alcohol. The first stage represents oxidative C–O coupling with liberation of the carboxyl group which is functionalized at the second stage thus affording ‘clicklike’ products with malonic linker.

Язык публикации: английский

DOI: 10.1016/j.mencom.2019.03.003