RUS  ENG
Полная версия
ЖУРНАЛЫ // Mendeleev Communications // Архив

Mendeleev Commun., 2018, том 28, выпуск 1, страницы 20–21 (Mi mendc1648)

Эта публикация цитируется в 2 статьях

Communications

Reaction of 1-(het)aryl-3-bromoprop-2-ynones with furans in solid metal oxides or salts: cross-coupling or cycloaddition?

D. N. Tomilin, L. N. Sobenina, M. D. Gotsko, I. A. Ushakov, B. A. Trofimov

A.E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences, Irkutsk, Russian Federation


Аннотация: 1-(Het)aryl-3-bromoprop-2-ynones react with 2-(2-furyl)pyrrole in the Al2O3 or K2CO3 dispersion (room temperature, 1 h) to afford the cross-coupling products either at the furan or pyrrole rings. Furan and 2-methylfuran with 3-bromo-1-phenylprop-2-ynone under the same conditions give the Diels–Alder cycloadducts, while furan-2-carbaldehyde andits acetals are inactive.

Язык публикации: английский

DOI: 10.1016/j.mencom.2018.01.004



© МИАН, 2025