N. I. Guranova, A. V. Varlamov, R. A. Novikov, A. V. Aksenov, T. N. Borisova, E. A. Sorokina, L. G. Voskresenskii, “Reaction of benzyne with 1,2,3,4-tetrahydroisoquinolines as an access to 1H-3-benzazepines”, Mendeleev Commun., 2018, том 28, выпуск 1,страницы 22

Эта публикация цитируется в 3 статьях

Reaction of benzyne with 1,2,3,4-tetrahydroisoquinolines as an access to 1H-3-benzazepines

N. I. Guranova^a, A. V. Varlamov^a, R. A. Novikov^b, A. V. Aksenov^c, T. N. Borisova^a, E. A. Sorokina^a, L. G. Voskresenskii^a

^a Peoples Friendship University of Russia (RUDN University), Moscow, Russian Federation
^b N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation
^c Department of Biology and Chemistry, Stavropol State University, Stavropol, Russian Federation

Аннотация: 1,2,3,4-Tetrahydroisoquinolines bearing phenacyl group at the nitrogen atom in their reaction with benzyne in acetonitrile undergo ring expansion to give 1H-3-benzazepines.

Ключевые слова: tetrahydroisoquinolines, benzyne, benzoazepines, Stevens rearrangement, aryne.

Язык публикации: английский

DOI: 10.1016/j.mencom.2018.01.005