S. A. Adonin, I. D. Gorokh, P. A. Abramov, I. V. Korolkov, M. N. Sokolov, V. P. Fedin, “A novel polybromide complex of bismuth – (Et4N)3{[Bi2Br9(Br2)}: synthesis and structural features”, Mendeleev Commun., 2018, том 28, выпуск 1,страницы 39

Эта публикация цитируется в 4 статьях

A novel polybromide complex of bismuth – (Et4N)3{[Bi2Br9(Br2)}: synthesis and structural features

S. A. Adonin^ab, I. D. Gorokh^b, P. A. Abramov^ab, I. V. Korolkov^ab, M. N. Sokolov^ac, V. P. Fedin^ab

^a A.V. Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, Novosibirsk, Russian Federation
^b Novosibirsk State University, Novosibirsk, Russian Federation
^c Alexander Butlerov Institute of Chemistry, Kazan Federal University, Kazan, Russian Federation

Аннотация: The polybromide complex (Et4N)3{[Bi2Br9](Br2)} was obtained by reaction of [BiBr6]3–, Br2 and tetraethylammonium bromide in 2 m HBr. In its crystal structure, bioctahedral [Bi2Br9]3– anions are connected by neutral Br2 linkers into infinite 1D chains via terminal bromide ligands.

Язык публикации: английский

DOI: 10.1016/j.mencom.2018.01.012