S. A. Lermontov, A. N. Malkova, N. A. Sipyagina, A. V. Semakov, A. Y. Baranchikov, V. K. Ivanov, “Methyl trifluoropyruvate – a new solvent for the production of fluorinated organic resorcinol–formaldehyde aerogels”, Mendeleev Commun., 2018, том 28, выпуск 1,страницы 102

Эта публикация цитируется в 4 статьях

Methyl trifluoropyruvate – a new solvent for the production of fluorinated organic resorcinol–formaldehyde aerogels

S. A. Lermontov^a, A. N. Malkova^a, N. A. Sipyagina^a, A. V. Semakov^a, A. Y. Baranchikov^b, V. K. Ivanov^bc

^a Institute of Physiologically Active Compounds, Federal Research Center of Problems of Chemical Physics and Medicinal Chemistry, Russian Academy of Sciences, Chernogolovka, Moscow Region, Russian Federation
^b N.S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation
^c National Research Tomsk Polytechnic University, Tomsk, Russian Federation

Аннотация: Resorcinol–formaldehyde aerogels obtained in methyl trifluoropyruvate (MTFP) possess a fluorinated matrix due to the mechanism of electrophilic substitution in the resorcinol moiety with the formation of C–C bond. The use of MTFP as a solvent also substantially accelerates the formaldehyde–resorcinol interaction.

Ключевые слова: resorcinol-formaldehyde aerogels, methyl trifluoropyruvate, fluorination, electrophilic substitution.

Язык публикации: английский

DOI: 10.1016/j.mencom.2018.01.035