P. S. Gribanov, Yu. D. Golenko, M. A. Topchiy, A. N. Philippova, N. Yu. Kirilenko, N. V. Krivoshchapov, G. K. Sterligov, A. F. Asachenko, M. V. Bermeshev, M. S. Nechaev, “One-pot two-step stannylation/Stille homocoupling of aryl bromides and iodides under solvent-free conditions”, Mendeleev Commun., 2018, том 28, выпуск 3,страницы 323

Эта публикация цитируется в 7 статьях

One-pot two-step stannylation/Stille homocoupling of aryl bromides and iodides under solvent-free conditions

P. S. Gribanov^ab, Yu. D. Golenko^a, M. A. Topchiy^ab, A. N. Philippova^b, N. Yu. Kirilenko^ab, N. V. Krivoshchapov^a, G. K. Sterligov^a, A. F. Asachenko^ab, M. V. Bermeshev^b, M. S. Nechaev^ab

^a Department of Chemistry, M.V. Lomonosov Moscow State University, Moscow, Russian Federation
^b A.V. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, Moscow, Russian Federation

Аннотация: A new highly efficient solvent-free method for aryl bromide (iodide) homocoupling comprising the use of Pd(OAc)2/PCy3 system in the presence of CsF is suitable for substrates bearing functional groups not tolerant to lithium-, magnesium-, zincorganic reagents and strong bases.

Ключевые слова: stannylation, Stille homocoupling, solvent-free reactions, cross-coupling, Pd-catalysis.

Язык публикации: английский

DOI: 10.1016/j.mencom.2018.05.032