L. O. Khafizova, L. I. Khusainova, T. V. Tyumkina, K. S. Ryazanov, N. R. Porod'ko, U. M. Dzhemilev, “An original catalytic synthesis of boriran-1-ols”, Mendeleev Commun., 2018, том 28, выпуск 6,страницы 577

Эта публикация цитируется в 6 статьях

An original catalytic synthesis of boriran-1-ols

L. O. Khafizova, L. I. Khusainova, T. V. Tyumkina, K. S. Ryazanov, N. R. Porod'ko, U. M. Dzhemilev

Institute of Petrochemistry and Catalysis, Ufa Federal Research Centre of the Russian Academy of Sciences, Ufa, Russian Federation

Аннотация: 2-Alkylboriran-1-ols were obtained in a one-pot process by hydrolysis of 1-fluoro- and 1-chloroboriranes in 90–92% yield. The starting 1-haloboriranes were generated by cycloboration of α-olefins with BCl3·SMe2 or BF3·THF in the presence of Mg metal (acceptor of halogen ions) and Cp2TiCl2 catalyst.

Язык публикации: английский

DOI: 10.1016/j.mencom.2018.11.003