I. V. Esarev, V. V. Gurzhiy, A. A. Selyutin, A. V. Laptenkova, A. I. Poddel'sky, N. L. Medvedskiy, A. I. Ponyaev, R. E. Trifonov, A. V. Eremin, “First example of a click-reaction on the aminate copper complexes: effect of reaction parameters”, Mendeleev Commun., 28:6 (2018), 606

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Communications

First example of a click-reaction on the aminate copper complexes: effect of reaction parameters

I. V. Esarev^a, V. V. Gurzhiy^b, A. A. Selyutin^b, A. V. Laptenkova^b, A. I. Poddel'sky^c, N. L. Medvedskiy^a, A. I. Ponyaev^a, R. E. Trifonov^ab, A. V. Eremin^ad

^a St. Petersburg State Institute of Technology (Technical University), St. Petersburg, Russian Federation
^b St. Petersburg State University, St. Petersburg, Russian Federation
^c G.A. Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences, Nizhnii Novgorod, Russian Federation
^d Peter the Great St. Petersburg Polytechnic University, St. Petersburg, Russian Federation

Аннотация: The hydrothermal reaction of NaN₃ with Cu(Phen)Cl₂ in acetonitrile solutions results in the formation of two complexes: new d⁹ mononuclear cis-[Cu^II(Phen)₂(mtz)₂]·H₂O and d¹⁰ coordination polymer catena-[Cu^I(Phen)(μ-CN)]_n (mtz is 5-methyltetrazolate anion and Phen is 1,10-phenanthroline). The process involves in situ formation of mtz ligand via cycloaddition of acetonitrile and azide (in the case of [Cu^II(Phen)₂(mtz)₂]) and cleavage of acetonitrile C–C bond (in the case of [Cu^I(Phen)(μ-CN)]_n). Both complexes were fully characterized by a comprehensive set of methods, including the single crystal X-ray diffraction data.

Язык публикации: английский

DOI: 10.1016/j.mencom.2018.11.014

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