D. I. Galimov, D. R. Gazeeva, R. G. Bulgakov, A. O. Terent'ev, “Chemiluminescence in decomposition of bridged 1,2,4,5-tetraoxanes catalyzed by ferrocene”, Mendeleev Commun., 27:4 (2017), 371

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Communications

Chemiluminescence in decomposition of bridged 1,2,4,5-tetraoxanes catalyzed by ferrocene

D. I. Galimov^a, D. R. Gazeeva^a, R. G. Bulgakov^b, A. O. Terent'ev^c

^a Institute of Petrochemistry and Catalysis, Ufa Federal Research Centre of the Russian Academy of Sciences, Ufa, Russian Federation
^b Institute of Molecule and Crystal Physics, Ufa Research Centre of the Russian Academy of Sciences, Ufa, Russian Federation
^c N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation

Аннотация: Chemiluminescence was observed in ferrocene-catalyzed decomposition of bridged 1,2,4,5-tetraoxanes, namely, 2,3,5,6-tetraoxabicyclo[2.2.1]heptanes. The chemi- and photoluminescence spectra revealed the main products and luminescence emitters to be β-diketones. The reaction intermediate, the OOH radical, was found to catalyze the decomposition of the 1,2,4,5-tetraoxanes.

Язык публикации: английский

DOI: 10.1016/j.mencom.2017.07.017