A. R. Tuktarov, A. A. Khuzin, A. R. Akhmetov, L. M. Khalilov, A. R. Tulyabaev, V. A. Barachevskiĭ, O. V. Venidiktova, U. M. Dzhemilev, “Covalent binding of fullerene C60 to dithienylethene as a promising approach to the preparation of new photochromic compounds”, Mendeleev Commun., 2016, том 26, выпуск 2,страницы 143

Эта публикация цитируется в 14 статьях

Covalent binding of fullerene C₆₀ to dithienylethene as a promising approach to the preparation of new photochromic compounds

A. R. Tuktarov^a, A. A. Khuzin^a, A. R. Akhmetov^a, L. M. Khalilov^a, A. R. Tulyabaev^a, V. A. Barachevskiĭ^b, O. V. Venidiktova^b, U. M. Dzhemilev^a

^a Institute of Petrochemistry and Catalysis, Ufa Federal Research Centre of the Russian Academy of Sciences, Ufa, Russian Federation
^b Photochemistry Center, FSRC ‘Crystallography and Photonics’, Russian Academy of Sciences, Moscow, Russian Federation

Аннотация: A dithienylethene-containing fullerocyclopropane was synthesized by the catalytic reaction of the carbon cluster with diazoalkane generated in situ by the oxidation of a corresponding photochrome hydrazone with MnO₂ in the presence of the Pd(acac)₂–2PPh₃–4Et₃Al catalyst, and the photochromic properties of the synthesized methanofullerene were evaluated.

Ключевые слова: [60]fullerene, dithienylethene, cycloaddition, metal complex catalysis, methanofullerene, DFT calculations, photochromism.

Язык публикации: английский

DOI: 10.1016/j.mencom.2016.03.021