Hydrothermal synthesis, crystal structure and magnetic properties of a new 3D MnII complex based on the flexible ligand 5-(4-pyridyl)methoxyisophthalic acid
aBengBu Medical College, Bengbu, P.R. China bZhengzhou University of Aeronautics, Zhengzhou, P.R. China cState Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing, P.R. China
Аннотация:
A new 3D coordination polymer [Mn2L2(H2O)2·2DMF· 2H2O]n [H2L = 5-(4-pyridyl)methoxyisophthalic acid] with a {42.6}2{44.62.87.102} net has been synthesized from H2L by a hydrothermal method. Magnetic susceptibility measurements indicated antiferromagnetic interaction between the adjacent MnII ions in the polymer.