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ЖУРНАЛЫ // Mendeleev Communications // Архив

Mendeleev Commun., 2016, том 26, выпуск 4, страницы 312–313 (Mi mendc2197)

Эта публикация цитируется в 10 статьях

Communications

A minor isomer of C84 fullerene, D6h-C84(24), captured as a trifluoromethylated derivative, C84(CF3)12

N. B. Tamm, S. I. Troyanov

Department of Chemistry, M.V. Lomonosov Moscow State University, Moscow, Russian Federation


Аннотация: An isomer of C84 fullerene, D3d-C84(24)(CF3)12, has been isolated by the HPLC method from the products of trifluoromethylation of C84 fullerene mixture. Its molecular structure has been determined by a single crystal X-ray diffraction using synchrotron radiation. In the addition pattern, 12 CF3 groups are arranged as a loop of edge-sharing para-C6(CF3)2 hexagons. Isomer D6h-C84(24) has been identified in the form of a derivative for the first time.

Язык публикации: английский

DOI: 10.1016/j.mencom.2016.07.015



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