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ЖУРНАЛЫ // Mendeleev Communications // Архив

Mendeleev Commun., 2024, том 34, выпуск 5, страницы 709–710 (Mi mendc228)

Communications

One-pot two-step synthesis of γ-keto sulfones in deep eutectic solvent

L. Yea, Zh. Zhaob, E.-x. Leic, L. Wangc

a Ningbo University of Finance and Economics, Zhejiang, P.R. China
b Ningbo University of Technology, Zhejiang, P.R. China
c School of Chemical and Pharmaceutical Engineering, Changzhou Vocational Institute of Engineering, Changzhou, P.R. China


Аннотация: Acidic deep eutectic solvent was prepared from choline chloride and trifluoromethanesulfonic acid at room temperature. Reaction between aromatic aldehydes and arylacetylenes in this solvent gave chalcones whose in situ reaction with sodium arenesulfinates in water successfully provided γ-keto sulfones in good yields. This deep eutectic solvent could be easily recovered and reused for several runs.

Ключевые слова: γ-keto sulfones, deep eutectic solvent, aromatic aldehydes, arylacetylenes, sodium arenesulfinates, one-pot synthesis.

Язык публикации: английский

DOI: 10.1016/j.mencom.2024.09.027



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