M. A. Epishina, A. S. Kulikov, N. V. Ignat'ev, M. Schulte, N. N. Makhova, “Nucleophilic aromatic cine-substitution of hydrogen: the ionic liquid-promoted von Richter reaction”, Mendeleev Commun., 25:1 (2015), 41

Эта публикация цитируется в 9 статьях

Communications

Nucleophilic aromatic cine-substitution of hydrogen: the ionic liquid-promoted von Richter reaction

M. A. Epishina^a, A. S. Kulikov^a, N. V. Ignat'ev^b, M. Schulte^b, N. N. Makhova^a

^a N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation
^b Ionic Liquid Research Laboratory, Merck KGaA, Darmstadt, Germany

Аннотация: Conversion of 4-R-nitrobenzenes into 3-R-benzoic acids under the action of KCN in the EtOH–H₂O mixture (the von Richter reaction) is significantly accelerated by ionic liquids thus allowing to extend the scope of the reaction. The finding is pioneering ionic liquid- promoted nucleophilic aromatic cine-substitution of hydrogen.

Язык публикации: английский

DOI: 10.1016/j.mencom.2015.01.015