I. S. Akhrem, L. V. Afanas'eva, I. M. Churilova, O. I. Artyushin, N. D. Kagramanov, “Chemo- and regioselective remote functionalization of nonanamides via sp3 C–H bond cleavage under superelectrophilic conditions”, Mendeleev Commun., 25:2 (2015), 124

Эта публикация цитируется в 5 статьях

Communications

Chemo- and regioselective remote functionalization of nonanamides via sp³ C–H bond cleavage under superelectrophilic conditions

I. S. Akhrem, L. V. Afanas'eva, I. M. Churilova, O. I. Artyushin, N. D. Kagramanov

A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation

Аннотация: Treatment of nonanamides C₈H₁₇C(O)NR₂ (R = H or Et) with superelectrophilic complex CBr₄·2AlBr₃ under CO atmosphere followed by quenching with nucleophiles NuH cleanly gives 7-methyl-7-(Nu-carbonyl)octanamide bifunctional derivatives.

Язык публикации: английский

DOI: 10.1016/j.mencom.2015.03.015

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