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ЖУРНАЛЫ // Mendeleev Communications // Архив

Mendeleev Commun., 2015, том 25, выпуск 3, страницы 182–184 (Mi mendc2343)

Эта публикация цитируется в 7 статьях

Communications

Base-promoted transformation of 2-C(O)R-1,8-bis(dimethylamino)naphthalenes into benzo[g]indole derivatives

S. G. Kachalkinaa, G. S. Borodkinb, A. F. Pozharskiia, A. S. Antonova, I. G. Borodkinab, Yu. F. Maltsevb, E. A. Filatovaa, A. Filarowskic, V. A. Ozeryanskiia

a Department of Chemistry, Southern Federal University, Rostov-on-Don, Russian Federation
b Institute of Physical and Organic Chemistry, Southern Federal University, Rostov-on-Don, Russian Federation
c Department of Chemistry, University of Wroclaw, Wroclaw, Poland


Аннотация: 1,8-Bis(dimethylamino)naphthalenes bearing 2-positioned trifluoroacetyl or ethoxycarbonyl group on treatment with 2-lithio-1,8-bis-dimethylamino)naphthalene undergo base-promoted transformation into benzo[g]indole derivatives in small to moderate yield, representing previously unknown mode of the pyrrole ring closure which proceeds via deprotonation of the NMe group.

Язык публикации: английский

DOI: 10.1016/j.mencom.2015.05.007



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