A. V. Artem'ev, N. K. Gusarova, S. F. Malysheva, N. A. Belogorlova, O. N. Kazheva, G. G. Alexandrov, O. A. Dyachenko, B. A. Trofimov, “Unexpected N,N’-coordination of tris(2-pyridyl)-phosphine chalcogenides to PdCl2”, Mendeleev Commun., 25:3 (2015), 196

Эта публикация цитируется в 14 статьях

Communications

Unexpected N,N’-coordination of tris(2-pyridyl)-phosphine chalcogenides to PdCl₂

A. V. Artem'ev^a, N. K. Gusarova^a, S. F. Malysheva^a, N. A. Belogorlova^a, O. N. Kazheva^b, G. G. Alexandrov^c, O. A. Dyachenko^b, B. A. Trofimov^a

^a A.E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences, Irkutsk, Russian Federation
^b Institute of Problems of Chemical Physics, Russian Academy of Sciences, Chernogolovka, Moscow Region, Russian Federation
^c N.S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation

Аннотация: Tris(2-pyridyl)phosphine chalcogenides Py₃P=X (X = O, S, Se) react with PdCl₂ or Li₂PdCl₄ to give the chelate complexes cis-[Pd(N,N’-Py₃P=X)Cl₂] in which Pd^II ion is square-planar coordinated to two pyridine nitrogen atoms of the ligand (κ²-N,N’).

Язык публикации: английский

DOI: 10.1016/j.mencom.2015.05.012

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