N. B. Tamm, S. I. Troyanov, “Structural study of minor C84 isomers as chlorofullerenes, C84(11)Cl22, C84(14)Cl22, C84(16)Cl22, and C84(16)Cl24”, Mendeleev Commun., 34:5 (2024), 734

Communications

Structural study of minor C₈₄ isomers as chlorofullerenes, C₈₄(11)Cl₂₂, C₈₄(14)Cl₂₂, C₈₄(16)Cl₂₂, and C₈₄(16)Cl₂₄

N. B. Tamm, S. I. Troyanov

Department of Chemistry, M.V. Lomonosov Moscow State University, Moscow, Russian Federation

Аннотация: Chlorofullerenes C₈₄Cl_22,24 were obtained by chlorination of minor C₈₄ isomers mixture with VCl₄ at 330 °C. An X-ray crystallographic study with the use of synchrotron radiation revealed the presence of C₈₄(11)Cl₂₂, C₈₄(14)Cl₂₂, C₈₄(16)Cl₂₂, and C₈₄(16)Cl₂₄ in the same crystal.

Ключевые слова: higher fullerenes, C₈₄, chlorination, minor isomers, structure elucidation.

Язык публикации: английский

DOI: 10.1016/j.mencom.2024.09.035