Novel approaches to pharmacology-oriented and energy rich organic nitrogen–oxygen systems

Organic compounds bearing semi-polar nitrogen–oxygen bonds are considered as perspective platform for designing socially important medications and high energy materials. Herein, recently developed original syntheses of monocyclic and fused 1,2,3,4-tetrazine 1,3-dioxides, various (methylene)bis(1-oxy-1-triazene 2-oxide) derivatives, furoxan-containing polyheterocyclic scaffolds and diastereo- or enantiomerically enriched functionalized aliphatic nitro compounds are summarized. Prospects for their practical applications are outlined.