V. O. Smirnov, A. S. Maslov, M. I. Struchkova, D. E. Arkhipov, A. D. Dilman, “Synthesis of S-difluoromethyl dithiocarbamates”, Mendeleev Commun., 25:6 (2015), 452

Эта публикация цитируется в 7 статьях

Communications

Synthesis of S-difluoromethyl dithiocarbamates

V. O. Smirnov^a, A. S. Maslov^ab, M. I. Struchkova^a, D. E. Arkhipov^c, A. D. Dilman^a

^a N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation
^b Department of Chemistry, M.V. Lomonosov Moscow State University, Moscow, Russian Federation
^c A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation

Аннотация: A method for preparation of S-difluoromethyl dithiocarbamates has been developed, which involves the treatment of secondary amines with carbon disulfide in methanol followed by S-difluoromethylation of the intermediate dithiocarbamate anion with difluorocarbene generated from (bromodifluoromethyl)trimethylsilane.

Язык публикации: английский

DOI: 10.1016/j.mencom.2015.11.018

	*Дополнительные материалы:*
		Supplementary_data_1.pdf	843.5 Kb