A. V. Orlova, Y. Yin, V. S. Petrov, P. S. Lemport, V. Yu. Kozhevnikova, V. G. Nenajdenko, V. V. Utochnikova, “Lanthanide complexes with (4,7-dichloro-1,10-phenanthroline-2,9-diyl)bis(pyrrolidin-1-ylmethanone): bifunctional materials for homogeneous catalysis and luminescent thermometry”, Mendeleev Commun., 34:6 (2024), 825

Communications

Lanthanide complexes with (4,7-dichloro-1,10-phenanthroline-2,9-diyl)bis(pyrrolidin-1-ylmethanone): bifunctional materials for homogeneous catalysis and luminescent thermometry

A. V. Orlova^a, Y. Yin^a, V. S. Petrov^a, P. S. Lemport^a, V. Yu. Kozhevnikova^ab, V. G. Nenajdenko^a, V. V. Utochnikova^ab

^a Department of Chemistry, M.V. Lomonosov Moscow State University, Moscow, Russian Federation
^b Department of Materials Science, M.V. Lomonosov Moscow State University, Moscow, Russian Federation

Аннотация: The first bifunctional materials for simultaneous catalysis and temperature measurements were obtained based on europium and ytterbium complexes with (4,7-dichloro-1,10- phenanthroline-2,9-diyl)bis(pyrrolidin-1-ylmethanone). The complexes demonstrated intense visible and NIR luminescence, the ability to homogeneously catalyze the Henry reaction, and high luminescence sensitivity to temperature (S_r = 1.7% K⁻¹).

Ключевые слова: lanthanide complexes, luminescence, homogeneous catalysis, luminescent thermometry, multifunctional materials, Henry reaction.

Язык публикации: английский

DOI: 10.1016/j.mencom.2024.10.018

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