A. A. Vasil'ev, S. E. Lyubimov, E. P. Serebryakov, V. A. Davankov, S. G. Zlotin, “Asymmetric Tsuji–Trost substitution in 3-acetoxy-1,3-diphenylpropene under phase-transfer conditions”, Mendeleev Commun., 2012, том 22, выпуск 1,страницы 39

Эта публикация цитируется в 7 статьях

Asymmetric Tsuji–Trost substitution in 3-acetoxy-1,3-diphenylpropene under phase-transfer conditions

A. A. Vasil'ev^a, S. E. Lyubimov^b, E. P. Serebryakov^a, V. A. Davankov^b, S. G. Zlotin^a

^a N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation
^b A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation

Аннотация: P*-Chiral diamidophosphite ligand-assisted Pd-catalyzed Tsuji–Trost reaction between dimethyl malonate and prochiral 3-acetoxy-1,3-diphenylpropene in organic solvents using potassium carbonate as the base affords the substitution product in quantitative yields and with enantioselectivities up to 99% ee.

Язык публикации: английский

DOI: 10.1016/j.mencom.2012.01.015