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ЖУРНАЛЫ // Mendeleev Communications // Архив
Mendeleev Commun., 2012, том 22, выпуск 4, страницы 187–188 (Mi mendc2784)
Эта публикация цитируется в 21 статьях

Tris(2-pyridyl)phosphine: a straightforward microwave-assisted synthesis from 2-bromopyridine and red phosphorus and coordination with cobalt(ii) dichloride

B. A. Trofimova, N. K. Gusarovaa, A. V. Artem'eva, S. F. Malyshevaa, N. A. Belogorlovaa, A. O. Korochevaa, O. N. Kazhevab, G. G. Alexandrovc, O. A. Dyachenkob

a A.E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences, Irkutsk, Russian Federation
b Institute of Problems of Chemical Physics, Russian Academy of Sciences, Chernogolovka, Moscow Region, Russian Federation
c N.S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation

Аннотация: Microwave irradiation of 2-bromopyridine with red phosphorus in the superbasic KOH/DMSO (H2O) suspension affords tris(2-pyridyl)phosphine in 53% yield; two molecules of tris(2-pyridyl)phosphine coordinate with CoCl2 by their six nitrogen atoms only to form [Co(2-Py3P)2]Cl2⋅8H2O complex having two phosphorus atoms beyond the coordination sphere.

Язык публикации: английский

DOI: 10.1016/j.mencom.2012.06.004


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