S. A. Rzhevskiy, O. V. Shurupova, A. F. Asachenko, N. M. Belov, A. V. Plutalova, E. S. Trofimchuk, R. V. Toms, E. V. Chernikova, I. P. Beletskaya, “Polymerization–cyclodepolymerization of polypropylene carbonate mediated by cobalt catalyst”, Mendeleev Commun., 34:6 (2024), 878

Эта публикация цитируется в 1 статье

Communications

Polymerization–cyclodepolymerization of polypropylene carbonate mediated by cobalt catalyst

S. A. Rzhevskiy^a, O. V. Shurupova^a, A. F. Asachenko^ab, N. M. Belov^b, A. V. Plutalova^b, E. S. Trofimchuk^b, R. V. Toms^c, E. V. Chernikova^ab, I. P. Beletskaya^ab

^a A.V. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, Moscow, Russian Federation
^b Department of Chemistry, M.V. Lomonosov Moscow State University, Moscow, Russian Federation
^c M.V. Lomonosov Institute of Fine Chemical Technologies, MIREA - Russian Technological University, Moscow, Russian Federation

Аннотация: The racemic salen complex of cobalt(iii) with pentafluorobenzoate axial ligand provides the synthesis of high molecular weight amorphous polypropylene carbonate and its full conversion into propylene carbonate.

Ключевые слова: carbon dioxide, epoxides, polycarbonates, catalysis, polymerization, cyclodepolymerization, cyclic carbonates.

Язык публикации: английский

DOI: 10.1016/j.mencom.2024.10.034

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