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ЖУРНАЛЫ // Mendeleev Communications // Архив

Mendeleev Commun., 2012, том 22, выпуск 4, страницы 208–210 (Mi mendc2793)

Эта публикация цитируется в 26 статьях

Binding of NO by nontransition metal complexes

E. V. Ilyakina, A. I. Poddel'sky, V. K. Cherkasov, G. A. Abakumov

G.A. Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences, Nizhnii Novgorod, Russian Federation

Аннотация: The first example of nitric oxide fixation by nontransition metal complexes was found: lead(II) and zinc(II) catecholato complexes readily react with nitric oxide to give the corresponding nitrosyl-containing mono-o-semiquinonates; the process of binding and transfer of NO can be easily monitored by EPR spectroscopy.

Ключевые слова: redox-active ligands, catecholate, lead(II), zinc(II), NO binding, EPR.

Язык публикации: английский

DOI: 10.1016/j.mencom.2012.06.013



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