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ЖУРНАЛЫ // Mendeleev Communications // Архив

Mendeleev Commun., 2023, том 33, выпуск 1, страницы 37–40 (Mi mendc300)

Эта публикация цитируется в 3 статьях

Communications

Halogen-substituted salicylhydroximate copper(II) metallacrowns: from synthesis and structures to novel applications

M. A. Katkovaa, G. S. Zabrodinaa, R. V. Rumyantceva, G. Yu. Zhigulina, M. S. Muravyevaab, M. P. Shuryginaac, S. A. Chesnokova, S. Yu. Ketkova

a G.A. Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences, Nizhnii Novgorod, Russian Federation
b Privolzhsky Research Medical University, Nizhny Novgorod, Russian Federation
c Alexander Butlerov Institute of Chemistry, Kazan Federal University, Kazan, Russian Federation


Аннотация: New halogen-substituted salicylhydroximate copper(II) metallacrowns were synthesized from Cu(OAc)2 and the corresponding salicylhydroxamic acids. Their molecular structure was determined by single crystal X-ray diffraction. The compounds obtained represent the first members of the metallacrown family that can be used as components of active initiators for the photopolymerization of oligo-carbonate dimethacrylate by visible light.

Ключевые слова: copper(ii) metallacrowns, organohalogen compounds, salicylhydroxamic acids, X-ray structure, DFT calculations, photo- polymerization of dimethacrylate.

Язык публикации: английский

DOI: 10.1016/j.mencom.2023.01.011



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