S. E. Lyubimov, I. V. Kuchurov, A. A. Vasil'ev, S. G. Zlotin, V. A. Davankov, “Asymmetric allylic alkylation in supercritical carbon dioxide using P*-chiral diamidophosphite ligands”, Mendeleev Commun., 2010, том 20, выпуск 3,страницы 143

Эта публикация цитируется в 11 статьях

Asymmetric allylic alkylation in supercritical carbon dioxide using P*-chiral diamidophosphite ligands

S. E. Lyubimov^a, I. V. Kuchurov^b, A. A. Vasil'ev^b, S. G. Zlotin^b, V. A. Davankov^a

^a A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation
^b N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation

Аннотация: P*-Chiral diamidophosphite ligands in the Pd-catalyzed allylic alkylation of (E)-1,3-diphenylallyl acetate in supercritical carbon dioxide provide enantioselectivities up to 90% ee. The catalytic performance is affected greatly by temperature, CO₂ pressures and structure of catalysts.

Язык публикации: английский

DOI: 10.1016/j.mencom.2010.05.006