R. G. Kostyanovsky, K. A. Lyssenko, O. N. Krutius, V. R. Kostyanovsky, “Isomorphism of chiral ammonium salts Ph(All)N+Et(Me)X–·CHCl3 †”, Mendeleev Commun., 2009, том 19, выпуск 1,страницы 19

Эта публикация цитируется в 3 статьях

Isomorphism of chiral ammonium salts Ph(All)N⁺Et(Me)X^–·CHCl₃ †

R. G. Kostyanovsky^a, K. A. Lyssenko^b, O. N. Krutius^a, V. R. Kostyanovsky^a

^a N.N. Semenov Federal Research Center for Chemical Physics, Russian Academy of Sciences, Moscow, Russian Federation
^b A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation

Аннотация: The title ammonium salts (X = Br, I) were synthesized, the identity of crystal structures for them (space groups P2₁2₁2₁, Z = 4) was found, spontaneous resolution of Ph(All)N⁺Et(Me)Br^–·CHCl₃ was performed, and the impossibility of replacement of the solvate molecule by CHBr₃ or CH₂Hal₂ (Hal = Cl, Br, I) was demonstrated by ¹H NMR and X-ray diffraction studies.

Язык публикации: английский

DOI: 10.1016/j.mencom.2009.01.008