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ЖУРНАЛЫ // Mendeleev Communications // Архив

Mendeleev Commun., 2009, том 19, выпуск 5, страницы 260–262 (Mi mendc3191)

Эта публикация цитируется в 15 статьях

The first example of the ortho-directing effect of the weakly coordinating substituent [–BF3] in the catalytic hydrodefluorination of the pentafluorophenyltrifluoroborate anion

N. Yu. Adonina, S. A. Prikhod'koa, V. V. Bardinb, V. N. Parmona

a G.K. Boreskov Institute of Catalysis, Siberian Branch of the Russian Academy of Sciences, Novosibirsk, Russian Federation
b N.N. Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch of the Russian Academy of Sciences, Novosibirsk, Russian Federation

Аннотация: The pentafluorophenyltrifluoroborate anion undergoes hydrodefluorination under the action of zinc in the presence of nickel complexes turning into the 2,3,4,5-tetrafluoroborate anion.

Ключевые слова: hydrodeboration, nickel complexes, fluorinated organoboron compounds.

Язык публикации: английский

DOI: 10.1016/j.mencom.2009.09.009



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