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ЖУРНАЛЫ // Mendeleev Communications // Архив

Mendeleev Commun., 2006, том 16, выпуск 4, страницы 234–237 (Mi mendc3602)

Эта публикация цитируется в 4 статьях

Acid-catalysed degradation of the organomercury intermediates of pentafluorophenylmercury bromide reduction near a mercury electrode

V. A. Kurmaza, A. B. Ershlerb

a Institute of Problems of Chemical Physics, Russian Academy of Sciences, Chernogolovka, Moscow Region, Russian Federation
b A.N. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Moscow, Russian Federation

Аннотация: The acid-catalysed protolysis of intermediates, formed either during one-electron reduction of substituted arylmercury salt (C6F5HgBr) or by the adsorption of bis(arylalkynyl)mercury compound [(PhC≡C)2Hg] on a Hg electrode has been found in lowacidic media (3 < pH < 6), whereas it was not observed in alkylmercury salt (PrnHgOAc).

Язык публикации: английский

DOI: 10.1070/MC2006v016n04ABEH002259



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