P. V. Novikov, O. R. Malyshev, K. A. Lyssenko, R. G. Kostyanovsky, “Resolution and racemization of nonbenzenoid atropenantiomers”, Mendeleev Commun., 2004, том 14, выпуск 6,страницы 310–312

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Mendeleev Commun., 2004, том 14, выпуск 6, страницы 310–312 (Mi mendc3923)

Эта публикация цитируется в 1 статье

Resolution and racemization of nonbenzenoid atropenantiomers

P. V. Novikov^a, O. R. Malyshev^b, K. A. Lyssenko^c, R. G. Kostyanovsky^a

^a N.N. Semenov Federal Research Center for Chemical Physics, Russian Academy of Sciences, Moscow, Russian Federation
^b N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation
^c A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation

Аннотация: The three-step synthesis of adduct 3 has been reinvestigated; enantiomers 3a and 3b have been separated by enantioselective chromatography and the racemization barrier of 3a was determined as ΔG⊋ = 24.4 kcal mol^–1 (16 °C).

Язык публикации: английский

DOI: 10.1070/MC2004v014n06ABEH002049

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