Mendeleev Commun., 2023, том 33, выпуск 3, страницы 357–359
(Mi mendc396)
Эта публикация цитируется в
3 статьях
(Cyclopentadienyl)neodymium borohydrides with auxiliary N3-heterocyclic ligands G. I. Sadrtdinova ab ,
D. A. Bardonov abc ,
K. A. Lyssenko d ,
M. E. Minyaev ac ,
I. E. Nifant'ev abe ,
D. M. Roitershtein abc a A.V. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, Moscow, Russian Federation b National Research University Higher School of Economics (HSE University), Moscow, Russian Federation c N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation d G.V. Plekhanov Russian University of Economics, Moscow, Russian Federation e Department of Chemistry, M.V. Lomonosov Moscow State University, Moscow, Russian Federation Аннотация:
Mononuclear [CpNd(BH4)2L] borohydrides comprising L = 1,3,5-trimethyl-1,3,5-triazacyclohexane (Me3tach) and L = 1,4,7-trimethyl-1,4,7-triazacyclononane (Me3tacn) were obtained and structurally characterized. Their catalytic
activity in coordination–insertion ring-opening polymerization of ε-caprolactone was studied.
Ключевые слова:
lanthanide complexes, neodymium complexes, cyclopentadienyl, borohydrides, crystal structure, polymerization, ε-caprolactone.
Язык публикации: английский
DOI:
10.1016/j.mencom.2023.04.019
© , 2025
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