E. Alcalde, L. Pérez-García, S. Ramos, J. F. Stoddart, S. A. Vignon, A. J. White, D. J. Williams, “Spontaneous resolution of a non-degenerate donor—acceptor [2]catenane”, Mendeleev Commun., 13:3 (2003), 100

Эта публикация цитируется в 14 статьях

Spontaneous resolution of a non-degenerate donor—acceptor [2]catenane

E. Alcalde^a, L. Pérez-García^a, S. Ramos^a, J. F. Stoddart^b, S. A. Vignon^b, A. J. White^c, D. J. Williams^c

^a Laboratori de Química Orgànica, Facultat de Farmàcia, Universitat de Barcelona, Barcelona, Spain
^b Department of Chemistry and Biochemistry, University of California, Los Angeles, USA
^c Department of Chemistry, Imperial College London, London, UK

Аннотация: The incorporation of a 3,5-bis(methylene)-1H-1,2,4-triazole unit into the macrocyclic polyether component of a donor–acceptor [2]catenane induces selectivity in the isomerization processes operating within the molecule, since it exists both in solution and in the solid state as only one of two possible translational isomers, and, upon crystallisation, undergoes spontaneous resolution under racemizing conditions.

Язык публикации: английский

DOI: 10.1070/MC2003v013n03ABEH001809