R. G. Kostyanovsky, V. Schurig, O. Trapp, K. A. Lyssenko, B. B. Averkiev, G. K. Kadorkina, A. V. Prosyanik, V. R. Kostyanovsky, “Chiral 1-alkoxyaziridines: resolution, nitrogen inversion, structure and diastereomeric transformations”, Mendeleev Commun., 2002, том 12, выпуск 4,страницы 137

Эта публикация цитируется в 18 статьях

Chiral 1-alkoxyaziridines: resolution, nitrogen inversion, structure and diastereomeric transformations

R. G. Kostyanovsky^a, V. Schurig^b, O. Trapp^b, K. A. Lyssenko^c, B. B. Averkiev^c, G. K. Kadorkina^a, A. V. Prosyanik^d, V. R. Kostyanovsky^a

^a N.N. Semenov Federal Research Center for Chemical Physics, Russian Academy of Sciences, Moscow, Russian Federation
^b Institut fuer Organische Chemie, Eberhard Karls Universitaet Tuebingen, Tuebingen, Germany
^c A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation
^d Ukrainian State University of Chemical Technology, Dnepropetrovsk, Ukraine

Аннотация: The resolution of enantiomers by chiral chromatography and the determination of nitrogen inversion activation parameters by dynamic chromatography have been carried out for aziridines 1–3; the structures of aziridines 4–7 have been studied; the complete diastereomeric transformation of (S,R)-(+)-8a into (R,R)-(–)-8b has been performed, and the conglomerate of high-melting diastereomer (±)-9 has been found.

Язык публикации: английский

DOI: 10.1070/MC2002v012n04ABEH001612