A. V. Budkova, V. G. Merkulov, R. E. Ivanov, M. N. Zharkov, I. V. Kuchurov, S. G. Zlotin, “Application of NO2/supercritical CO2 system for safe and selective nitration of adamantanes and tertiary alkyl bromides”, Mendeleev Commun., 2023, том 33, выпуск 4,страницы 461

Эта публикация цитируется в 5 статьях

Application of NO2/supercritical CO2 system for safe and selective nitration of adamantanes and tertiary alkyl bromides

A. V. Budkova^ab, V. G. Merkulov^ab, R. E. Ivanov^a, M. N. Zharkov^a, I. V. Kuchurov^a, S. G. Zlotin^a

^a N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation
^b D.Mendeleev University of Chemical Technology of Russia, Moscow, Russian Federation

Аннотация: A concise safe approach for selective nitration and nitroxylation of tert-alkanes, in particular adamantane, and tert-alkyl bromides utilizing NO2 in supercritical CO2 medium has been established. Major reaction products were tert-alkyl nitro compounds and tert-alkyl nitrates depending on the reaction conditions.

Ключевые слова: nitroalkanes, nitrates, nitrogen dioxide, supercritical carbon dioxide, adamantane, tert-alkyl bromides.

Язык публикации: английский

DOI: 10.1016/j.mencom.2023.06.006