E. A. Trusova, M. V. Tsodikov, E. V. Slivinskii, G. G. Hernandes, O. V. Bukhtenko, T. N. Zhdanova, D. I. Kochubey, J. A. Navio, “The effect of the structure of Cu-Ti oxide systems obtained by sol-gel synthesis on the nature of catalytic centres and catalytic activity in low-temperature CO oxidation”, Mendeleev Commun., 1998, том 8, выпуск 3,страницы 102

Эта публикация цитируется в 11 статьях

The effect of the structure of Cu-Ti oxide systems obtained by sol-gel synthesis on the nature of catalytic centres and catalytic activity in low-temperature CO oxidation

E. A. Trusova^a, M. V. Tsodikov^a, E. V. Slivinskii^a, G. G. Hernandes^a, O. V. Bukhtenko^a, T. N. Zhdanova^a, D. I. Kochubey^b, J. A. Navio^c

^a A.V. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, Moscow, Russian Federation
^b G.K. Boreskov Institute of Catalysis, Siberian Branch of the Russian Academy of Sciences, Novosibirsk, Russian Federation
^c University of Seville, Seville, Spain

Аннотация: It has been shown by X-ray diffraction analysis, EXAFS and XPS methods and in experiments on the low-temperature oxidation of CO that two types of catalytic oxidation centres are formed during sol-gel synthesis of single-phase Cu-Ti oxide systems (0.5-5.0 mass% Cu) based on anatase: the first type involves Cu+ ions in the [111] crystal planes, while the second type involves Cu²⁺ ions, which isomorphically substitute titanium ions in the [100] planes of TiO₂.

Язык публикации: английский

DOI: 10.1070/MC1998v008n03ABEH000663