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ЖУРНАЛЫ // Mendeleev Communications // Архив

Mendeleev Commun., 1997, том 7, выпуск 2, страницы 50–51 (Mi mendc4777)

Эта публикация цитируется в 12 статьях

1,7-Sigmatropic shifts of the phenylsulfanyl group along the perimeter of the cycloheptatriene ring

G. A. Dushenkoa, I. E. Mikhailova, A. Zschunkeb, N. Hakamc, C. Mueggec, V. I. Minkina

a Institute of Physical and Organic Chemistry, Southern Federal University, Rostov-on-Don, Russian Federation
b Federal Institute for Materials Research and Testing, Berlin, Germany
c Department of Chemistry, Humboldt University, Berlin, Germany

Аннотация: Rapid and reversible migrations of the phenylsulfanyl group around the seven-membered ring of 7-phenylsulfanylcyclohepta- 1,3,5-triene have been proved to proceed through successive 1,7-sigmatropic shifts with an energy barrier (ΔG298) in the range of 19.5−20.1 kcal mol–1.

Язык публикации: английский

DOI: 10.1070/MC1997v007n02ABEH000669



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