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ЖУРНАЛЫ // Mendeleev Communications // Архив

Mendeleev Commun., 1996, том 6, выпуск 1, страницы 9–11 (Mi mendc4888)

Эта публикация цитируется в 8 статьях

Crown thioethers and 1,4-dithiacyclanes immobilized on silica carrier: preparation and studies of complexation affinity towards metal ions

E. I. Troyanskiia, M. S. Pogosyana, N. M. Samoshinaa, G. I. Nikishina, V. V. Samoshinb, L. K. Shpigunc, N. E. Kopytovac, P. M. Kamilovac

a N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation
b Department of Chemistry, University of the Pacific, Stockton, California, USA
c N.S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation

Аннотация: Crown thioethers and their non-macrocyclic analogues have been immobilized on a silica matrix coated with ω-(triethoxysilyl)-undecanoic acid. Thiacrown modified silica carriers were found to be highly suitable as complex-forming adsorbents for silver(I) and gold(III) ions under dynamic conditions, and application of their complexation affinity for preparation of solid-state electrochemical sensors based on composite carbon-paste electrodes has been demonstrated.

Язык публикации: английский

DOI: 10.1070/MC1996v006n01ABEH000554



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