A. G. Tolstikov, O. V. Tolstikova, G. A. Tolstikov, “Hexa-O-acetyl-D-gentiobial in enantioselective synthesis of lysocerebrosides and their conjugates”, Mendeleev Commun., 1996, том 6, выпуск 4,страницы 128

Эта публикация цитируется в 2 статьях

Hexa-O-acetyl-D-gentiobial in enantioselective synthesis of lysocerebrosides and their conjugates

A. G. Tolstikov^a, O. V. Tolstikova^b, G. A. Tolstikov^b

^a G.K. Boreskov Institute of Catalysis, Siberian Branch of the Russian Academy of Sciences, Novosibirsk, Russian Federation
^b N.N. Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch of the Russian Academy of Sciences, Novosibirsk, Russian Federation

Аннотация: Hexa-O-acetyl-D-gentiobial 1 and its decyclization product (2E,4S,5R)-4-acetoxy-5-hydroxy-6-(2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyloxy)hex-2-enal 2 have been used to synthesize O-glycosylated aminodiols 9,10,15 that model the structure of natural lysocerebrosides. Compounds 9,10,15 can serve as basic components to produce N-acylated conjugates with derivatives of arachidonic and glycyrrhizic acids.

Язык публикации: английский

DOI: 10.1070/MC1996v006n04ABEH000612