O. S. Korneva, L. G. Menchikov, E. S. Koltun, O. M. Nefedov, “Regio- and Stereoselective Preparation of 3-Trimethylsilylallylic Alcohols by Solvolysis of 2-Trimethylsilylic Derivatives of 1-Bromo- and 1,1-Dibromocyclo-propanes in the Presence of CuSO4”, Mendeleev Commun., 5:4 (1995), 135

Эта публикация цитируется в 3 статьях

Regio- and Stereoselective Preparation of 3-Trimethylsilylallylic Alcohols by Solvolysis of 2-Trimethylsilylic Derivatives of 1-Bromo- and 1,1-Dibromocyclo-propanes in the Presence of CuSO₄

O. S. Korneva^a, L. G. Menchikov^a, E. S. Koltun^b, O. M. Nefedov^a

^a N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation
^b Higher Chemical College of the Russian Academy of Sciences, D.I. Mendeleev University of Chemical Technology of Russia, Moscow, Russian Federation

Аннотация: The interaction of 1-bromo- and 1,1-dibromocyclopropanes with an equimolar quantity of CuSO₄ in a DMSO–water mixture (molar ratio halocyclopropane:CuSO₄·5H₂O:DMSO:H₂O = 1:1:10–12:14–16) proceeds via cleavage of the three-membered ring to selectively give the most thermodynamically stable isomers of the corresponding 3-trimethylsilyl-substituted allylic or 2-bromoallylic alcohols.

Язык публикации: английский

DOI: 10.1070/MC1995v005n04ABEH000492