V. N. Kalinin, V. V. Derunov, L. Maat, J. K. Park, H. Schmidhammer, “Synthesis of π-Complexes of Codeine with Iron and Molybdenum”, Mendeleev Commun., 5:6 (1995), 222

Эта публикация цитируется в 3 статьях

Synthesis of π-Complexes of Codeine with Iron and Molybdenum

V. N. Kalinin^a, V. V. Derunov^a, L. Maat^b, J. K. Park^c, H. Schmidhammer^d

^a A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation
^b Laboratory of Organic Chemistry and Catalysis, Delft University of Technology, Delft, the Netherlands
^c Dong Kook Pharmaceutical Co., Ltd., Seoul, Korea
^d Institute of Pharmacy, University of Innsbruck, Innsbruck, Austria

Аннотация: Treatment of 6β-chloro-6-deoxycodeine 1 or 8β-bromo-8-deoxypseudocodeine 2 with Fe(CO)₅ or Fe₂(CO)₉ yields 6-demethoxythebaine 3 and the π-diene iron complex 4; compound 1 or 2 reacts with Mo(CO)₆ to give the π-allylic molybdenum complexes 5 and 6, respectively.

Язык публикации: английский

DOI: 10.1070/MC1995v005n06ABEH000535